MOLECULES | KovacsResearch

Fe(III)tame-N2S3 ORTEP

Synthetic analogue of unmodified NHase active site

trenSFe_NO2 ORTEP

Nitrite-bound Fe-thiolate complex

Mn(III)-OOtBu ORTEP

1st crystallographically characterized Mn-alkylperoxo

Binuclear Mn peroxo

Dioxygen-derived peroxo

(trenS)Fe-NO

Probing the dioxygen binding site with NO

(Pr,Pr)Fe(II)

Reactive 5-coordinate superoxo precursor

(trenS)Fe(IV)=O

1st crystallographically characterized thiolate-ligated high-valent oxo

Fe(II)cyclam-PrS

A five coordinate thiolate-ligated complex that reduces superoxide

Nitrite-bound iron thiolate